Chiral GC Analysis of Enantiomerically Pure Fenchone in Essential Oils

被引：22

作者：

Ravid, Uzi ^{[1
]}

Putievsky, Eli ^{[1
]}

Katzir, Irena ^{[1
]}

Ikan, Raphael ^{[2
]}

机构：

[1] Agr Res Org, Inst Field Crops, IL-31999 Newe Yaar, Haifa Post, Israel

[2] Hebrew Univ Jerusalem, Dept Organ Chem, Nat Prod Lab, IL-91904 Jerusalem, Israel

来源：

FLAVOUR AND FRAGRANCE JOURNAL | 1992年 / 7卷 / 03期

关键词：

(+)-Fenchone; (-)-Fenchone; Enantiomeric purity; Essential oils;

D O I：

10.1002/ffj.2730070314

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Enantiomerically pure (+)-fenchone was detected in the essential oils of wild, bitter and sweet fennel plants and seeds. Enantiomerically pure (-)-fenchone was detected in the oils of wormwood, tansy and cedarleaf. Determination of the enantiomeric purity of fenchone in laboratory-made essential oils and in essential oils and samples of fenchone from commercial sources, was performed by direct capillary gas chromatography on a Lipodex (R) E column.

引用

页码：169 / 172

页数：4

共 22 条

[1] MONOTERPENE PATTERNS IN JUNIPERUS AND THUJA SPECIES [J].

BANTHORPE, DV ;

DAVIES, HS ;

GATFORD, C ;

WILLIAMS, SR .

PLANTA MEDICA, 1973, 23 (01) :64-69

[2]

Bauer K., 1985, COMMON FRAGRANCE FLA, P47

[3]

Cowart B. J., COMMUNICATION

[4]

Furia T. E., 1975, FENAROLIS HDB FLAVOR, V2, P202

[5]

Guenther E., 1949, ESSENTIAL OILS, V2, P418

[6]

Heth G., EXPERIENTIA IN PRESS

[7] GAS-CHROMATOGRAPHIC ENANTIOMER SEPARATION OF CHIRAL KETONES - ORDER OF ELUTION AND CONFIGURATIONAL STABILITY OF OXIME DERIVATIVES [J].

KONIG, WA ;

SCHMIDT, E ;

KREBBER, R .

CHROMATOGRAPHIA, 1984, 18 (12) :698-700

[8] SEPARATION OF CHIRAL KETONES BY ENANTIOSELECTIVE GAS-CHROMATOGRAPHY [J].

KONIG, WA ;

BENECKE, I ;

ERNST, K .

JOURNAL OF CHROMATOGRAPHY, 1982, 253 (02) :267-270

[9]

KONIG WA, 1990, HRC-J HIGH RES CHROM, V13, P328

[10]

Konig WA, 1989, J HIGH RES CHROMATOG, V12, P732, DOI DOI 10.1002/JHRC.1240121108

← 1 2 3 →