REDUCTION OF KETONES BY DIHYDROGEN OR HYDROGEN-TRANSFER CATALYZED BY A RUTHENIUM COMPLEX OF THE HYDRIDOTRIS(3,5-DIMETHYL)PYRAZOLYL BORATE LIGAND

被引：27

作者：

VICENTE, C ^{[1
]}

SHULPIN, GB ^{[1
]}

MORENO, B ^{[1
]}

SABOETIENNE, S ^{[1
]}

CHAUDRET, B ^{[1
]}

机构：

[1] CNRS, CHIM COORDINAT LAB, UPR 8241, F-31077 TOULOUSE, FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 98卷 / 01期

关键词：

HYDROGEN; KETONES; PYRAZOLYL DERIVATIVE; REDUCTION; RUTHENIUM;

D O I：

10.1016/1381-1169(95)00045-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydride complexes Tp*RuH(H-2)(2) (1) and Tp*RuH(COD) (2) (Tp* = hydridotris(3,5-dimethyl)pyrazolyl borate) show good catalytic activity for the reduction of unactivated ketones either by dihydrogen or by hydrogen transfer from alcohols in basic media.

引用

页码：L5 / L8

页数：4

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