TRANSFORMATIONS PRECEDING AMORPHIZATION IN CR-TI AND CR-TI-FE BETA-PHASES

被引:10
作者
WIRZ, C [1 ]
BLATTER, A [1 ]
BALTZER, N [1 ]
VONALLMEN, M [1 ]
机构
[1] CENDRES & MET SA,CH-2501 BIEL,SWITZERLAND
来源
PHYSICAL REVIEW B | 1990年 / 42卷 / 11期
关键词
D O I
10.1103/PhysRevB.42.6993
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The nonequilibrium bcc solid solutions of Cr-Ti and Cr-Ti-Fe, obtained by quenching bulk material at a moderate cooling rate, undergo partial solid-state amorphization during annealing at a relatively low temperature in the spinodal range. Cyclic and isothermal measurements of the specific heats, the coefficients of thermal expansion, and the resistivities, as well as x-ray diffraction, were performed to examine the vitrification reactions and the configurations involved. The data reveal that vitrification involves a sequence of events led by an exothermic reaction that appears to be displacive in nature. The resulting structure, although crystalline by configuration, displays characteristic features of amorphous materials such as a glass transition. Configurational amorphization only occurs gradually at temperatures above the glass transition. © 1990 The American Physical Society.
引用
收藏
页码:6993 / 6999
页数:7
相关论文
共 34 条
[1]   REVERSIBLE STRUCTURAL RELAXATION IN METALLIC GLASSES [J].
ALTOUNIAN, Z .
MATERIALS SCIENCE AND ENGINEERING, 1988, 97 :461-468
[2]   MEASUREMENT AND INTERPRETATION OF GLASS-TRANSITION TEMPERATURE-TG IN A NUMBER OF METALLIC SYSTEMS [J].
BAXI, H ;
MASSALSKI, TB .
MATERIALS SCIENCE AND ENGINEERING, 1988, 97 :291-296
[3]   STRAIN-DRIVEN SOLID-STATE AMORPHIZATION OF BINARY TRANSITION-METAL ALLOYS [J].
BLATTER, A ;
VONALLMEN, M .
MATERIALS SCIENCE AND ENGINEERING, 1988, 97 :93-95
[4]   STRUCTURE AND TRANSFORMATION KINETICS IN SPONTANEOUSLY VITRIFIED CR-TI ALLOYS [J].
BLATTER, A ;
GFELLER, J ;
VONALLMEN, M .
JOURNAL OF THE LESS-COMMON METALS, 1988, 140 :317-325
[5]   ROLE OF DEFECTS FOR THE SPONTANEOUS VITRIFICATION OF BETA-(CR,TI) [J].
BLATTER, A ;
KAMBLI, U ;
WIRZ, C ;
GIOVANOLI, R ;
DYRBYE, K ;
BOTTIGER, J .
PHYSICAL REVIEW B, 1989, 40 (18) :12503-12506
[6]   SPONTANEOUS VITRIFICATION IN CR-TI BULK ALLOYS [J].
BLATTER, A ;
VONALLMEN, M ;
BALTZER, N .
JOURNAL OF APPLIED PHYSICS, 1987, 62 (01) :276-280
[7]   THE PROCESS OF SPONTANEOUS VITRIFICATION EVALUATED BY CALORIMETRY [J].
BLATTER, A ;
KOCH, N ;
KAMBLI, U .
JOURNAL OF THE LESS-COMMON METALS, 1988, 145 (1-2) :81-88
[8]   REVERSIBLE AMORPHIZATION IN LASER-QUENCHED TITANIUM-ALLOYS [J].
BLATTER, A ;
VONALLMEN, M .
PHYSICAL REVIEW LETTERS, 1985, 54 (19) :2103-2106
[9]   DISORDERED MATERIALS - A SURVEY OF AMORPHOUS SOLIDS [J].
CHENG, YT ;
JOHNSON, WL .
SCIENCE, 1987, 235 (4792) :997-1002
[10]   LIQUID-GLASS TRANSITION, A FREE-VOLUME APPROACH [J].
COHEN, MH ;
GREST, GS .
PHYSICAL REVIEW B, 1979, 20 (03) :1077-1098