SPIN ORBIT STATE DISTRIBUTION OF ATOMIC OXYGEN (3PJ) PRODUCED BY PHOTODISSOCIATION OF NITROGEN-DIOXIDE

被引：56

作者：

MIYAWAKI, J

TSUCHIZAWA, T

YAMANOUCHI, K

TSUCHIYA, S

机构：

[1] Department of Pure and Applied Sciences, College of Arts and Sciences, The University of Tokyo Komaba, Meguro-ku, Tokyo

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 165卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(90)85423-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The spin-orbit state distribution of O(3PJ) produced by photodissociation of NO2 was determined by application of a tunable VUV laser. The distributions in the dissociation by 355, 337 and 266 nm excitation were all similar, i.e. 3P2:3P1:3P0≈1:0.19:0.03, while the photolysis at 212 nm yielded 1:0.35:0.08. © 1990.

引用

页码：168 / 170

页数：3

共 9 条

[1] ELECTRONIC-STRUCTURE OF NITROGEN-DIOXIDE .1. MULTICONFIGURATION SELF-CONSISTENT-FIELD CALCULATION OF LOW-LYING ELECTRONIC STATES [J].

GILLISPIE, GD ;

KHAN, AU ;

WAHL, AC ;

HOSTENY, RP ;

KRAUSS, M .

JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (08) :3425-3444

[2] BROADLY TUNABLE VACUUM ULTRAVIOLET EXTREME-ULTRAVIOLET RADIATION GENERATED BY RESONANT 3RD-ORDER FREQUENCY-CONVERSION IN KRYPTON [J].

HILBER, G ;

LAGO, A ;

WALLENSTEIN, R .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1987, 4 (11) :1753-1764

[3] PHOTODISSOCIATION OF NO2. INTERNAL ENERGY-DISTRIBUTION AND ANISOTROPIES IN THE FRAGMENTS [J].

MONS, M ;

DIMICOLI, I .

CHEMICAL PHYSICS, 1989, 130 (1-3) :307-324

[4]

MOORE CE, 1971, NSRDSNBS35

[5]

Okabe H., 1978, PHOTOCHEMISTRY SMALL

[6] STUDY OF NITROGEN-DIOXIDE (2B-2(2) PHOTODECOMPOSITION TO O(D-1) AND NO(PI-2) IN ITS SECOND PREDISSOCIATION REGION 2500-2139 A [J].

USELMAN, WM ;

LEE, EKC .

JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (05) :1948-1955

[7]

YAMANOUCHI K, 1988, J SPECTROSC SOC JAPA, V37, P110

[8] LASER PHOTOFRAGMENT SPECTROSCOPY OF THE NO2 DISSOCIATION AT 337 NM - A NON-STATISTICAL DECAY PROCESS [J].

ZACHARIAS, H ;

GEILHAUPT, M ;

MEIER, K ;

WELGE, KH .

JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (01) :218-225

[9]

ZACHARIAS H, 1983, ENERGY STORAGE REDIS, P107

← 1 →