COMPLETE H-1 AND C-13 ASSIGNMENT OF SOME CUBANE DERIVATIVES BY 2D NMR-SPECTROSCOPY

被引：15

作者：

AXENROD, T

LIANG, B

BASHIRHASHEMI, A

DAVE, PR

REDDY, DS

机构：

[1] ARDEC,GEO CTR INC,LAKE HOPATCONG,NJ 07849

[2] USA,CTR RES DEV & ENGN CTR,PICATINNY ARSENAL,NJ 07806

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1991年 / 29卷 / 01期

关键词：

CUBANES; ONE-BOND; C-13-H COUPLING CONSTANTS;

D O I：

10.1002/mrc.1260290117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 13C and 1H chemical shift values of 31 cubanes ranging from mono‐ to hexa‐substituted derivatives were recorded in CDCl3 solution and the spectra were fully assigned using, where necessary, 2D 13C–H shift correlated spectra optimized for either one‐bond or long‐range 13C–H couplings. The one‐bond 13C–H coupling constants for the cubyl carbon resonances were also measured and tabulated. Copyright © 1991 John Wiley & Sons Ltd.

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页码：88 / 91

页数：4

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