NAPHTHO[2,3-D][1,2,3]OXADIAZOLE

被引：9

作者：

BLOCHER, A ^{[1
]}

ZELLER, KP ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST ORGAN CHEM,MORGENSTELLE,W-7400 TUBINGEN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期

关键词：

D O I：

10.1002/anie.199114761

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not the o-quinone diazide 1 but the title molecule 3 results from the deprotonation of diazonium salt 2. Compound 3 is the first preparatively realized example of a 1,2,3-oxadiazole. The high likelihood of the formation of 3 is probably due to the destabilization of the o-quinone and o-quinone bismethide structures in 1, which are passed over in favor of the lower energy naphthalene unit in the transformation to 3.

引用

页码：1476 / 1477

页数：2

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