CHEMISTRY OF HETEROMETALLIC CLUSTER COMPOUNDS PREPARED BY CONDENSATION OF GROUP-6 METAL ACETYLIDE AND GROUP-8 BINARY CARBONYL-COMPLEXES

被引：10

作者：

CHI, Y

机构：

[1] Department of Chemistry, National Tsing Hua University, Hsinchu

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1992年 / 39卷 / 06期

关键词：

HETERONUCLEAR CLUSTER; HETEROMETALLIC; TUNGSTEN; MOLYBDENUM; OSMIUM; RUTHENIUM; ACETYLIDE; ALKYNE;

D O I：

10.1002/jccs.199200093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemistry of trinuclear and tetranuclear heterometallic acetylide complexes, LWOs3(CO)11(C=CR) and LWM2(CO)8(C=CR), L = Cp and Cp*; M = Os and Ru, is presented. Included in this account are syntheses, characterization and reactivity, with a particular focus on reactions with disubstituted alkyne molecules. The reactivity and fluxionality of these acetylide complexes provides a plausible model for ligand-mediated metal-core rearrangement and the transformation of small organic molecules on catalytic metal surfaces.

引用

收藏

页码：591 / 601

页数：11

相关论文

共 71 条

[1] A SYSTEMATIC ENTRY TO BUTTERFLY-TYPE [M4(CO)12(MU-4-XY) CLUSTERS [J].

BANTEL, H ;

HANSERT, B ;

POWELL, AK ;

TASI, M ;

VAHRENKAMP, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (08) :1059-1060

[2] CARBONYL LIGANDS FROM ALKYNES - OXIDATIVE DECARBONATION OF ACETYLIDE BRIDGED COMPLEXES [J].

BERNHARDT, W ;

VAHRENKAMP, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 383 (1-3) :357-366

[3] OXIDATIVE DECARBONATION OF AN ACETYLIDE LIGAND [J].

BERNHARDT, W ;

VAHRENKAMP, H .

ORGANOMETALLICS, 1986, 5 (11) :2388-2389

[4] STRUCTURE OF AND BONDING IN AN ALKYNE-NONACARBONYLTRIIRON COMPLEX . A NEW TYPE OF IRON-ACETYLENE INTERACTION [J].

BLOUNT, JF ;

DAHL, LF ;

HOOGZAND, C ;

HUBEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (02) :292-&

[5] ORGANOMETALLIC CHEMISTRY OF VINYLIDENE AND RELATED UNSATURATED CARBENES [J].

BRUCE, MI .

CHEMICAL REVIEWS, 1991, 91 (02) :197-257

[6] CLUSTER CHEMISTRY .64. STUDY OF THE PYROLYSIS OF RU3(MU-DPPF)(CO)10 (DPPF = 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE) - X-RAY STRUCTURES OF RU3(MU-H)(MU-3-(ETA-1,ETA-2-C6H4)PPH(ETA-C5H4)FE(ETA-C5H4PPH2))(CO)8, RU3((MU-P(C6H4)-ETA-C5H4)FE(ETA-C5H4PPH2))(MU-CO)(CO)8, RU3(MU-3-ETA-1,ETA-1,ETA-2-C6H4)(MU-PPH2)(MU-PPHFC)(CO)7, RU3(MU-H)(MU-3-(ETA-1,ETA-5-PPH2C5H3)FE(ETA-C5H4PPH2))(CO)7, AND RU4(MU-4-PFC)(MU-4-C6H4)(MU-CO)(CO)10 (FC = FE(ETA-C5H5)(ETA-C5H4)) [J].

BRUCE, MI ;

HUMPHREY, PA ;

BINSHAWKATALY, O ;

SNOW, MR ;

TIEKINK, ERT ;

CULLEN, WR .

ORGANOMETALLICS, 1990, 9 (11) :2910-2919

[7] A QUARTER-CENTURY OF ORGANOMETALLICS - MOST OF IT DOWN-UNDER [J].

BRUCE, MI .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 400 (1-2) :321-340

[8] SOME MORE TRANSITION-METAL ACETYLIDES [J].

BRUCE, MI ;

HUMPHREY, MG ;

MATISONS, JG ;

ROY, SK ;

SWINCER, AG .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (09) :1955-1961

[9] THE REACTION OF A BRIDGED VINYLIDENEDI-IRON COMPLEX WITH COBALT, IRON, AND MANGANESE CARBONYL SPECIES - X-RAY CRYSTAL-STRUCTURES OF THE COMPLEXES [FE3(MU-3-CME)(MU-CO)2(CO)6(ETA-C5H5)] AND [CO3FE(MU-4-C=CH2)(MU-CO)2(CO)7(ETA-C5H5)] [J].

BRUN, P ;

DAWKINS, GM ;

GREEN, M ;

MILLS, RM ;

SALAUN, JY ;

STONE, FGA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (07) :1357-1362

[10] HETEROBIMETALLIC COMPOUNDS LINKED BY HETERODIFUNCTIONAL LIGANDS [J].

BULLOCK, RM ;

CASEY, CP .

ACCOUNTS OF CHEMICAL RESEARCH, 1987, 20 (05) :167-173

← 1 2 3 4 5 6 7 8 →