VISIBLE-LIGHT SENSITIZATION BY CIS-BIS(THIOCYANATO)BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATO)RUTHENIUM(II) OF A TRANSPARENT NANOCRYSTALLINE ZNO FILM PREPARED BY SOL-GEL TECHNIQUES

被引：194

作者：

REDMOND, G

FITZMAURICE, D

GRAETZEL, M

机构：

[1] NATL UNIV IRELAND UNIV COLL DUBLIN,DEPT CHEM,DUBLIN 4,IRELAND

[2] ECOLE POLYTECH FED LAUSANNE,INST CHIM PHYS,CH-1015 LAUSANNE,SWITZERLAND

来源：

CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 05期

关键词：

D O I：

10.1021/cm00041a020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transparent nanocrystalline ZnO films have been prepared on a conducting glass substrate by sol-gel techniques. Their sensitization by adsorption of a ruthenium-based complex and subsequent incorporation as the light harvesting unit in a regenerative photoelectrochemical cell are described. The resulting device has a monochromatic incident photon-to-current conversion efficiency of 13% at 520 nm.

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页码：686 / 691

页数：6

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