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SYNTHESIS AND PROPERTIES OF ANNULENE POLYOXIDES

被引：26
作者：
ELIX, JA
机构：
[1] Chemistry Department, Australian National University, Canberra, ACT
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 09期
关键词：
D O I：
10.1071/CH9691951
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A convenient synthesis of the higher annulene polyoxides is described. Sucrose was converted into 5-chloromethylfurfural which on reaction with triphenylphosphine gave the corresponding phosphonium salt. Treatment of this salt with lithium ethoxide accomplished a self-Wittig condensation and cyclic products isolated included [18]annulene trioxide, two isomers of [24]annulene tetroxide, two isomers of [30]annulene pentoxide, and an isomer of [36]annulene hexoxide. The properties of these compounds are discussed in relation to their aromaticity. © 1969, CSIRO. All rights reserved.
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页码：1951 / &
相关论文
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