NOVEL CATALYSTS FOR THE CARBONYLATION OF METHANOL

被引：100

作者：

DILWORTH, JR ^{[1
]}

MILLER, JR ^{[1
]}

WHEATLEY, N ^{[1
]}

BAKER, MJ ^{[1
]}

SUNLEY, JG ^{[1
]}

机构：

[1] BP CHEM LTD, HULL RES & TECHNOL CTR, KINGSTON HULL HU12 8DS, YORKS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001579

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium(I) carbonyl complexes containing phosphino-thiolate and thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, [Rhl(2)(CO)(2)](-); the crystal structure of one procatalyst, [Rh(SC(6)H(4)PPh(2))(CO)](2), is reported.

引用

页码：1579 / 1581

页数：3

共 28 条

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