ELECTROCHEMICAL STUDIES ON NEUTRAL TRIPLE-BRIDGED DI-RUTHENIUM COMPOUNDS

被引：15

作者：

ARTHUR, T ^{[1
]}

CONTRERAS, R ^{[1
]}

HEATH, GA ^{[1
]}

HEFTER, G ^{[1
]}

LINDSAY, AJ ^{[1
]}

RIACH, DJA ^{[1
]}

STEPHENSON, TA ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 04期

关键词：

D O I：

10.1016/S0022-328X(00)91864-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Voltammetric studies reveal that, like [Ru2Cl4(PPh3)4(CO)], triply-bridged complexes [Ru2Cl4L5] (L = PClPh2, PMePh2, PEt2Ph) are reversibly oxidized to [Ru2Cl4L5]+. The mixed valence complexes [Ru2Cl5L3Y] (L = PPh3, P(tol)3; Y = CO, CS) undergo a corresponding reduction to [Ru2Cl5L3Y]-; whereas [Ru2Cl5L4] (L = PEt2Ph, As(tol)3) and [Ru2Cl6(AsPh3)3] are both reduced and oxidised in reversible one-electron steps. For the bridging (RuCl3Ru)z+ moiety, the redox series z = 1, 2, 3, 4 is established. © 1979.

引用

页码：C49 / C54

页数：6

共 5 条

[1] ELECTROCHEMICAL STUDIES ON MONOMERIC RUTHENIUM COMPLEXES [J].

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[2] ELECTROCHEMICAL STUDIES ON TRIPLE-BRIDGED DI-RUTHENIUM(II) COMPOUNDS [J].

HEATH, GA ;

HEFTER, G ;

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STEPHENSON, TA .

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[3] BLUE RUTHENIUM CHLORIDE COMPLEXES AND THEIR OXIDATION PRODUCTS [J].

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INORGANIC CHEMISTRY, 1971, 10 (12) :2755-&

[4] BLUE CHLOROAMMINE COMPLEXES OF RUTHENIUM [J].

MERCER, EE ;

GRAY, LW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (18) :6426-&

[5] NEW THIOCARBONYL COMPLEXES OF RUTHENIUM [J].

STEPHENSON, TA ;

SWITKES, ES ;

ARMIT, PW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (11) :1134-1139

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