TETRANUCLEAR COPPER(II) COMPLEXES - COPPER(II) COMPLEXES OF SCHIFF-BASES DERIVED FROM HISTAMINE AND SALICYLALDEHYDE OR 2-PYRIDINECARBALDEHYDE

被引：22

作者：

NAKAO, Y ^{[1
]}

MORI, W ^{[1
]}

OKUDA, N ^{[1
]}

NAKAHARA, A ^{[1
]}

机构：

[1] OSAKA UNIV,COLL GEN EDUC,INST CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)93408-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of copper(II) ions with the Schiff bases derived from histamine and salicylaldehyde or 2-pyridinecarbaldehyde were investigated in acidic and basic media. The copper(II) complexes obtained from the reactions in acidic solutions were mononuclear complexes I and II, while those from the reactions in basic solutions were tetranuclear complexes III and IV, in which the four copper(II) ions were tetrahedrally arranged. A study on magnetic property (4.2-300 K) of the tetranuclear complexes by the Faraday method suggested the presence of antiferromagnetic interactions between the four copper(II) ions. © 1979.

引用

页码：1 / 4

页数：4

共 10 条

[1]

Bertrand J. A., 1970, INORG CHIM ACTA, V4, P203

[2] 5-CO-ORDINATE COPPER(2) IN A CUBANE-TYPE STRUCTURE [J].

BERTRAND, JA ;

KELLY, JA ;

KIRKWOOD, CE .

CHEMICAL COMMUNICATIONS, 1968, (21) :1329-&

[3] ANOMALOUS PARAMAGNETISM OF COPPER ACETATE [J].

BLEANEY, B ;

BOWERS, KD .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1119) :451-465

[4] MAGNETISM ELECTRONIC SPECTRA AND STRUCTURE OF TRANSITION METAL ALKOXIDES .6. CHROMIUM(3) CHLORO ALKOXIDES [J].

DUBICKI, L ;

KAKOS, GA ;

WINTER, G .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1968, 21 (06) :1461-&

[5] MAGNETIC EXCHANGE INTERACTIONS IN IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES [J].

KOLKS, G ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5804-5806

[6] IMIDAZOLATE-BRIDGED COMPLEXES OF COPPER(II) [J].

KOLKS, G ;

FRIHART, CR ;

RABINOWITZ, HN ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) :5720-5721

[7]

MORI W, 1971, 24TH P ANN M CHEM SO, V2, P762

[8] CRYSTAL-STRUCTURE OF BOVINE CU, ZN SUPEROXIDE-DISMUTASE AT 3 A RESOLUTION - CHAIN TRACING AND METAL LIGANDS [J].

RICHARDSON, JS ;

THOMAS, KA ;

RUBIN, BH ;

RICHARDSON, DC .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1975, 72 (04) :1349-1353

[9] INTERACTIONS OF HISTIDINE AND OTHER IMIDAZOLE DERIVATIVES WITH TRANSITION-METAL IONS IN CHEMICAL AND BIOLOGICAL-SYSTEMS [J].

SUNDBERG, RJ ;

MARTIN, RB .

CHEMICAL REVIEWS, 1974, 74 (04) :471-517

[10] PROTON DISSOCIATION CONSTANT OF PYRROLE INDOLE AND RELATED COMPOUNDS [J].

YAGIL, G .

TETRAHEDRON, 1967, 23 (06) :2855-&

← 1 →