OBSERVATION OF DIPOLE-BOUND CH3CN- FOLLOWING ELECTRON-ATTACHMENT TO CH3CN CLUSTERS

被引：29

作者：

HASHEMI, R ^{[1
]}

ILLENBERGER, E ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST PHYS & THEORET CHEM,TAKUSTR 3,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 17期

关键词：

D O I：

10.1021/j100170a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron attachment to acetonitrile clusters proceeds via two resonances at 3 and 8.5 eV, yielding ionic fragments (CH2CN-, CN-, etc.) and complexes of the form (CH2CN-.(CH3CN)n). In addition CH3CN- is exclusively formed within the resonance at higher energy. This ion is likely to represent a dipole-supported state.

引用

页码：6402 / 6403

页数：2

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