REACTIONS OF H-2, D2 WITH HG(6(3)P0) OR HG(6(3)P2) - PRODUCT ROTATIONAL STATE DISTRIBUTIONS

被引：8

作者：

BRAS, N

JEANNET, JC

BUTAUX, J

PERRIN, D

机构：

[1] Département de Recherches Physiques, Université Pierre et Marie Curie, Tour 22, 75252 Paris Cedex 05, 4, place Jussieu

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 95卷 / 02期

关键词：

D O I：

10.1063/1.461179

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The initial rotational state distributions of the HgH(upsilon = 0) and HgD(upsilon = 0) molecules produced in the reactions of Hg(6 3P0) with H-2, D2 have been determined. These distributions differ from the ones previously determined with Hg in the 6 3P1 state. This difference may be due to the decrease of the reaction exothermicity when Hg(6 3P1) is replaced by Hg(6 3P0). As for the reaction with Hg(6 3P2), it seems from a time analysis that there is some production of molecules in the higher rotational levels, nevertheless more work is necessary to conclude about the Hg(6 3P2) reactivity.

引用

页码：1006 / 1010

页数：5

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