STRUCTURE OF 2,11-DIOXA[3.3]ORTHOCYCLOPHANE

被引:24
作者
OKAJIMA, T [1 ]
WANG, ZH [1 ]
FUKAZAWA, Y [1 ]
机构
[1] HIROSHIMA UNIV, FAC SCI, DEPT CHEM, HIROSHIMA 730, JAPAN
关键词
D O I
10.1246/cl.1991.37
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conformational analysis of the title compound using an X-ray diffraction, molecular mechanics and ring current calculations is presented. The chair type structure found in its crystalline state is almost identical to that of its dithia analogue. However, the structure in solution is quite different from its crystalline structure.
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页码:37 / 40
页数:4
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