ASYMMETRIC HETERO-DIELS-ALDER REACTION CATALYZED BY STABLE AND EASILY PREPARED CAB CATALYSTS

被引：76

作者：

GAO, QZ ^{[1
]}

MARUYAMA, T ^{[1
]}

MOURI, M ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT APPL CHEM,NAGOYA 46401,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 07期

关键词：

D O I：

10.1021/jo00033a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stable chiral (acyloxy)borane (CAB) complex is prepared in situ by mixing tartaric acid derivative and arylboric acid at room temperature. A solution of the catalyst is effective to catalyze hetero Diels-Alder reaction to produce dihydropyrone derivatives of high optical purities.

引用

页码：1951 / 1952

页数：2

共 16 条

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