CATALYTIC ACTIVITY OF ACID-TREATED MONTMORILLONITE IN POLAR AND NONPOLAR REACTION MEDIA

被引：64

作者：

RHODES, CN ^{[1
]}

BROWN, DR ^{[1
]}

机构：

[1] LEEDS METROPOLITAN UNIV,CATALYSIS RES UNIT,LEEDS LS1 3HE,W YORKSHIRE,ENGLAND

来源：

CATALYSIS LETTERS | 1994年 / 24卷 / 3-4期

关键词：

MONTMORILLONITE CATALYST; ACID CATALYSIS; ACID-TREATED CLAYS; ACID-ACTIVATED CLAYS;

D O I：

10.1007/BF00811801

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic activity of acid-treated montmorillonite clay towards Bronsted acid catalysed reactions is shown to be highly dependent on the degree of acid treatment received by the clay. Using two contrasting model reactions, one involving highly polar reactants and the other a non-polar reactant, the optimum treatment conditions for an acid-treated clay catalyst are also shown to depend upon the type of reaction being catalysed. In addition, the role of exchangeable Al3+ ions in generating catalytically active acid sites in the two reactions is investigated.

引用

页码：285 / 291

页数：7

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