THE STRUCTURE OF CP(2)TIME(2)

被引：55

作者：

THEWALT, U

WOHRLE, T

机构：

[1] Sektion für Röntgen- und Elektronenbeugung der Universität Ulm

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

TITANIUM; METALLOCENE; CYCLOPENTADIENYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87024-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of dimethyltitanocene, Cp(2)TiMe(2), has been determined: monoclinic, space group P2(1)/n, lattice constants (at -100 degrees C) a = 6.818(2), b = 11.571(2), c = 13.387(3) Angstrom, beta=92.36(2)degrees, and Z=4. It is isostructural with Cp(2)ZrMe(2) and Cp(2)HfMe(2). The Ti-C(sigma) bond lengths are 2.170(2) and 2.181(2) Angstrom and the C(sigma)-TiC(sigma) angle is 91.3(1)degrees.

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页码：C17 / C19

页数：3

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