HYDRODENITROGENATION OF QUINOLINE OVER HIGH-SURFACE-AREA MO2N

被引:94
作者
LEE, KS [1 ]
ABE, H [1 ]
REIMER, JA [1 ]
BELL, AT [1 ]
机构
[1] UNIV CALIF BERKELEY,DEPT CHEM ENGN,BERKELEY,CA 94720
关键词
D O I
10.1006/jcat.1993.1004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reaction pathway far the hydrodenitrogenation of quinoline over Mo2N has been investigated. Quinoline is found to undergo a rapid hydrogenation to form 1,2,3,4,-tetrahydroquinoline. This product then reacts more slowly to form 2-propylaniline, which, in turn, undergoes hydrogenolysis of the CN bond in the saturated ring to farm propylbenzene. No evidence is found for propylcyclohexane. © 1993 by Academic Press, Inc.
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页码:34 / 40
页数:7
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