REACTIONS OF CRIEGEE INTERMEDIATES IN THE GAS-PHASE

被引：141

作者：

HATAKEYAMA, S ^{[1
]}

AKIMOTO, H ^{[1
]}

机构：

[1] UNIV TOKYO, ADV SCI TECHNOL RES CTR, MEGURO KU, TOKYO 153, JAPAN

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1994年 / 20卷 / 3-5期

关键词：

D O I：

10.1163/156856794X00432

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of Criegee intermediates in the gas phase are reviewed. These intermediates are formed by the reaction of olefins with ozone. In the gas phase Criegee intermediates have a biradical character. Initially they are formed as vibrationally hot species. After deactivation by collision with a third body, they can participate in bimolecular reactions with aldehydes, NO(x), SO2, water, and so on. Reaction mechanisms are discussed.

引用

页码：503 / 524

页数：22

共 69 条

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