THE MECHANISM OF ACTION OF SUGAR ACETALS AS NUCLEATING-AGENTS FOR POLYPROPYLENE

被引：83

作者：

SMITH, TL ^{[1
]}

MASILAMANI, D ^{[1
]}

BUI, LK ^{[1
]}

KHANNA, YP ^{[1
]}

BRAY, RG ^{[1
]}

HAMMOND, WB ^{[1
]}

CURRAN, S ^{[1
]}

BELLES, JJ ^{[1
]}

BINDERCASTELLI, S ^{[1
]}

机构：

[1] CHATHAM HIGH SCH,CHATHAM,NJ 07928

来源：

MACROMOLECULES | 1994年 / 27卷 / 12期

关键词：

D O I：

10.1021/ma00090a006

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We studied the nucleation of polypropylene via experimental measurements and molecular modeling, and we propose that sugar acetal nucleators stabilize the helical form of polypropylene at the molecular level. Through FTIR techniques, we established that the nucleators dibenzylidene sorbitol (DBS) and trinaphthylidene sorbitol are chemically stable in molten polypropylene. Using solid-state NMR, we determined that DBS is dispersed to particles 32 angstrom in diameter. These particles are three orders of magnitude smaller than the 1-10-mum size expected in the literature. DSC was employed to evaluate the nucleating ability of our nucleators. Through molecular modeling, we demonstrated that nucleating ability can be correlated with van der Waals attractions of the individual nucleator molecules with the helical form of polypropylene. A correlation was not seen when hydrogen bonded nucleator dimers were used. The model correctly predicted that one TNS diastereomer nucleates polypropylene and that the other diastereomer does not.

引用

页码：3147 / 3155

页数：9

共 36 条

[1] NUCLEAR-SPIN DIFFUSION BETWEEN POLYURETHANE MICROPHASES [J].