NEUTRON-DIFFRACTION STUDY ON FORMATION AND STRUCTURE OF DXTAS2 AND HXNBS2

被引：45

作者：

RIEKEL, C

REZNIK, HG

SCHOLLHORN, R

WRIGHT, CJ

机构：

[1] AERE,HARWELL OX11 0RA,OXFORDSHIRE,ENGLAND

[2] UNIV MUNSTER,INST ANORGAN CHEM,D-4400 MUNSTER,FED REP GER

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 11期

关键词：

D O I：

10.1063/1.437363

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cathodic reduction of 2H-TaS2 in D2SO4 was investigated by transient neutron powder diffractometry. Deuterium was found to enter the lattice in a regular way. The structural model proposed implies a strong Ta-D bond. Single crystal neutron diffraction data on H 0.76NbS2 confirm the position of hydrogen in a three-center metal bond inside the dichalcogenide layers. Structural data are in accordance with inelastic neutron scattering data. © 1979 American Institute of Physics.

引用

页码：5203 / 5212

页数：10

共 26 条

[1] CHEMICAL-REACTIONS OF TAS2 (H-2 PHASE) [J].