7-NORBORNADIENYLIDENE - NEW MEMBER OF THE C7H6 ENERGY SURFACE

被引:22
作者
BROWN, WT [1 ]
JONES, WM [1 ]
机构
[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32601
关键词
D O I
10.1021/jo01331a031
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
7-Norbornadienylidene, generated by pyrolysis of the corresponding N-nitrosourea, competitively loses carbon to give benzene and rearranges to bicyclo[3.2.0]-heptatriene which either dimerizes, opens to cycloheptatrienylidene-cycloheptatetraene, or rearranges to fulveneallene. © 1979, American Chemical Society. All rights reserved.
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页码:3090 / 3092
页数:3
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