OPTICAL-TRANSITIONS OF SM3+ IN OXIDE GLASSES

被引:92
作者
BOEHM, L
REISFELD, R
SPECTOR, N
机构
[1] Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem
关键词
D O I
10.1016/0022-4596(79)90060-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Eigenvectors of the 4f5 electronic configuration of Sm3+ were calculated in intermediate coupling, and used to obtain the reduced matrix elements U(λ). Absorption spectra of Sm3+ were recorded in phosphate, borate, germanate and tellurite glasses. The Judd-Ofelt Ωλ's intensity parameters were then deduced from the measured oscillator strengths by least-squares fitting. Radiative transition probabilities and integrated cross-sections of stimulated emissions are obtained. Calculated branching ratios and decay lifetimes are compared with the experimental values. © 1979.
引用
收藏
页码:75 / 78
页数:4
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