INVERSE AMINE-STABILIZED SULFENES F2C=SO2 AND FHC=SO2

被引：7

作者：

PRITZKOW, H ^{[1
]}

RALL, K ^{[1
]}

REIMANNANDERSEN, S ^{[1
]}

SUNDERMEYER, W ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 01期

关键词：

D O I：

10.1002/anie.199000601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrophilic C atom distinguishes the two title sulfenes from other sulfenes, in which the S atom is electrophilic. This follows from the structures of the Et3N adducts. which in these cases are present as zwitterions 1 and 2 respectively, and do not have the general structure A. 2 is formed from FH2CSO2C1 and Et3N, 1 by aminolysis of the dithietane 3. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：60 / 61

页数：2

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