ONE-ELECTRON OXIDATION OF CARBOXYLATES BY HEXACHLOROOSMATE(V) ION

被引：8

作者：

EBERSON, L

NILSSON, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期

关键词：

D O I：

10.1039/c39920001041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexachloroosmate(v) cleanly oxidizes tetrabutylammonium tert-butylcyanoacetate to decarboxylative-coupling products, meso- and rac-2,3-di-tert-butylsuccinonitrile, thus constituting the first metal ion-based oxidant to be found to simulate properly this aspect of the Kolbe anodic oxidation of carboxylates.

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页码：1041 / 1042

页数：2

相关论文

共 28 条

[1] PEROXIDE DECOMPOSITION AND CAGE EFFECT [J].

BRAUN, W ;

RAJBENBACH, L ;

EIRICH, FR .

JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (09) :1591-&

[2] SYNTHESIS, REDOX BEHAVIOR, AND SPIN-TRAP PROPERTIES OF 2,6-DI-TERT-BUTYLNITROSOBENZENE (DTBN) [J].

CERRI, V ;

FREJAVILLE, C ;

VILA, F ;

ALLOUCHE, A ;

GRONCHI, G ;

TORDO, P .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (06) :1447-1450

[3] HYDRATION OF SPIN-TRAP CATIONS AS A SOURCE OF HYDROXYL ADDUCTS [J].

CHANDRA, H ;

SYMONS, MCR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (16) :1301-1302

[4] SPECTROSCOPIC AND KINETIC CHARACTERISTICS OF AROYLOXYL RADICALS .2. BENZOYLOXYL AND RING-SUBSTITUTED AROYLOXYL RADICALS [J].

CHATEAUNEUF, J ;

LUSZTYK, J ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (09) :2886-2893

[5] 1ST SPECTROSCOPIC AND ABSOLUTE KINETIC-STUDIES ON (ALKOXYCARBONYL)OXYL RADICALS AND AN UNSUCCESSFUL ATTEMPT TO OBSERVE CARBAMOYLOXYL RADICALS [J].

CHATEAUNEUF, J ;

LUSZTYK, J ;

MAILLARD, B ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) :6727-6731

[6] ELECTRONEGATIVELY SUBSTITUTED CARBOCATIONS [J].

CREARY, X .

CHEMICAL REVIEWS, 1991, 91 (08) :1625-1678

[7]

DEHNICKE K, 1980, Z NATURFORSCH B, V35, P1525

[8] ELECTRON-TRANSFER REACTIONS IN ORGANIC-CHEMISTRY .9. ACYLOXYLATION AND OR DEBROMODIMERIZATION INSTEAD OF ELECTRON-TRANSFER IN THE REACTION BETWEEN TRIS(4-BROMOPHENYL)AMMONIUMYL AND ALIPHATIC CARBOXYLATES [J].

EBERSON, L ;

LARSSON, B .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1986, 40 (03) :210-225

[9] THE REACTION BETWEEN TRIS(4-BROMOPHENYL)AMINIUM ION AND ACETATE ION IS AN ELECTROPHILIC REACTION [J].

EBERSON, L ;

OLOFSSON, B .

ACTA CHEMICA SCANDINAVICA, 1989, 43 (07) :698-701

[10] ELECTRON-TRANSFER REACTIONS .19. OUTER-SPHERE ELECTRON-TRANSFER REACTIONS BETWEEN HEXACHLOROOSMATE(V) AND ORGANIC-COMPOUNDS [J].

EBERSON, L ;

NILSSON, M .

ACTA CHEMICA SCANDINAVICA, 1990, 44 (10) :1062-1070