RING-OPENING REACTIONS OF OXABICYCLIC COMPOUNDS AS A ROUTE TO CYCLIC AND ACYCLIC COMPOUNDS WITH MULTIPLE STEREOCENTERS

被引：134

作者：

LAUTENS, M

机构：

[1] Department of Chemistry, University of Toronto, Toronto, M5S 1A1, ON

来源：

SYNLETT | 1993年 / 03期

关键词：

D O I：

10.1055/s-1993-22393

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ring opening of oxabicyclic compounds with a variety of nucleophiles can serve as a useful reaction for the synthesis of cyclic and acyclic compounds with multiple stereocenters. Highly regio- and stereoselective reactions have been observed with organocuprates, silylcuprates, organolithium reagents and organomagnesium compounds.

引用

页码：177 / 185

页数：9

共 99 条

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