SYNTHESIS OF OPTICALLY PURE, DIFFERENTIALLY PROTECTED 1,4-MANNOSYL-D-MYO-INOSITOL AND 1,6-MANNOSYL-D-MYO-INOSITOL DERIVATIVES FROM 7-OXABICYCLO[2.2.1]HEPTAN-2-ONE

被引：15

作者：

ARJONA, O ^{[1
]}

DEDIOS, A ^{[1
]}

MONTERO, C ^{[1
]}

PLUMET, J ^{[1
]}

机构：

[1] UNIV COMPLUTENSE,FAC QUIM,DEPT QUIM ORGAN 1,E-28040 MADRID,SPAIN

来源：

TETRAHEDRON | 1995年 / 51卷 / 33期

关键词：

D O I：

10.1016/0040-4020(95)00524-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Efficient procedures to prepare 4-O-mannosyl conduritol B derivatives from mannosyl oxanorbornanes are described. The osmium-catalyzed cis-dihydroxylation of the corresponding 1-O-acetates displays high pi-facial selectivity syn to the acetate functionality to produce 1,4- and 1,6-mannosyl-D-myo-inositol derivatives.

引用

页码：9191 / 9200

页数：10

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