NITRITE-SELECTIVE ELECTRODE BASED ON AN ELECTROPOLYMERIZED COBALT PHTHALOCYANINE

被引：70

作者：

ALLEN, JR

FLORIDO, A

YOUNG, SD

DAUNERT, S

BACHAS, LG

机构：

[1] UNIV KENTUCKY,CTR MEMBRANE SCI,LEXINGTON,KY 40506

[2] UNIV POLITECN CATALUNYA,DEPT ENGN QUIM,E-08028 BARCELONA,SPAIN

来源：

ELECTROANALYSIS | 1995年 / 7卷 / 08期

关键词：

NITRITE; POTENTIOMETRY; COBALT PHTHALOCYANINE;

D O I：

10.1002/elan.1140070803

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cobalt(II) 4,4',4'',4'''-tetraaminophthalocyanine was electropolymerized on glassy carbon by cyclic voltammetry. The formed polymeric films were shown to interact selectively with anions and were used in the design of ion-selective electrodes. Different polymerization conditions, as well as different conditioning solutions and buffer systems, were investigated in order to optimize the response of the electrodes. The electrodes were found to be most selective for nitrite. The slopes of the calibration plots were sub-Nernstian and the detection limit for nitrite was 1.7 x 10(-4)M.

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页码：710 / 713

页数：4

相关论文

共 34 条

[1] HYDROXIDE ION-SELECTIVE POLYMERIC MEMBRANE-COATED WIRE ELECTRODE BASED ON OXOMOLYBDENUM(V) TETRAPHENYLPORPHYRIN COMPLEX [J].

ABE, H ;

KOKUFUTA, E .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (05) :1360-1364

[2] ANION SELECTIVITY OF METALLOPORPHYRINS IN MEMBRANES [J].

AMMANN, D ;

HUSER, M ;

KRAUTLER, B ;

RUSTERHOLZ, B ;

SCHULTHESS, P ;

LINDEMANN, B ;

HALDER, E ;

SIMON, W .

HELVETICA CHIMICA ACTA, 1986, 69 (04) :849-854

[3] POTENTIOMETRIC AND FIBER OPTIC SENSORS FOR PH BASED ON AN ELECTROPOLYMERIZED COBALT PORPHYRIN [J].

BLAIR, TL ;

ALLEN, JR ;

DAUNERT, S ;

BACHAS, LG .

ANALYTICAL CHEMISTRY, 1993, 65 (15) :2155-2158

[4] MECHANISM OF IONIC AND REDOX SENSITIVITY OF P-TYPE CONDUCTING POLYMERS .2. EXPERIMENTAL-STUDY OF POLYPYRROLE [J].

BOBACKA, J ;

GAO, ZQ ;

IVASKA, A ;

LEWENSTAM, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 368 (1-2) :33-41

[5] MN(III) PORPHYRIN-BASED THIOCYANATE-SELECTIVE MEMBRANE ELECTRODES - CHARACTERIZATION AND APPLICATION IN FLOW-INJECTION DETERMINATION OF THIOCYANATE IN SALIVA [J].

BROWN, DV ;

CHANIOTAKIS, NA ;

LEE, IH ;

MA, SC ;

PARK, SB ;

MEYERHOFF, ME ;

NICK, RJ ;

GROVES, JT .

ELECTROANALYSIS, 1989, 1 (06) :477-484

[6] INFLUENCE OF PORPHYRIN STRUCTURE ON ANION SELECTIVITIES OF MANGANESE(III) PORPHYRIN BASED MEMBRANE ELECTRODES [J].

CHANIOTAKIS, NA ;

CHASSER, AM ;

MEYERHOFF, ME ;

GROVES, JT .

ANALYTICAL CHEMISTRY, 1988, 60 (02) :185-188

[7] SALICYLATE-SELECTIVE MEMBRANE-ELECTRODE BASED ON TIN(IV) TETRAPHENYLPORPHYRIN [J].

CHANIOTAKIS, NA ;

PARK, SB ;

MEYERHOFF, ME .

ANALYTICAL CHEMISTRY, 1989, 61 (06) :566-570

[8]

COLLISON ME, 1989, THESIS U MICHIGAN

[9] ANION-SELECTIVE ELECTRODES BASED ON ELECTROPOLYMERIZED PORPHYRIN FILMS [J].

DAUNERT, S ;

WALLACE, S ;

FLORIDO, A ;

BACHAS, LG .

ANALYTICAL CHEMISTRY, 1991, 63 (17) :1676-1679

[10]

DAUNERT S, 1989, PROG CLIN BIOL RES, V61, P215

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