COMPLEXES OF 2,2'-AZOPYRIDINE WITH IRON(2) COBALT(2) NICKEL(2) COPPER(1) AND COPPER(2) . AN INFRARED STUDY

被引：209

作者：

BALDWIN, DA

LEVER, ABP

PARISH, RV

机构：

[1] Departments of Chemistry, University of Manchester, Institute of Science and Technology, Manchester, Great Britain

[2] York University, Ontario, Downsview

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 01期

关键词：

D O I：

10.1021/ic50071a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Vibrational spectroscopy in both the conventional and far-infrared regions, electronic spectroscopy, and magnetism are used to characterize a series of coordination complexes of 2,2′-azopyridine. Complexes of the title ions with ligand to metal ratios of 3:1, 2:1, or 1:2 are described. The nickel(II) and iron(II) derivatives are six-coordinate, while both six-coordinate and four-coordinate tetrahedral complexes of cobalt(Il) and copper are reported. Evidence is presented indicative of a very strong interaction between the spin-paired iron(II) atom and the ligand. © 1969, American Chemical Society. All rights reserved.

引用

页码：107 / &

共 77 条

[1] COMPLEXES OF AZOBENZENES AND SCHIFF BASES [J].

BAGGA, MM ;

PAUSON, PL ;

PRESTON, FJ ;

REED, RI .

CHEMICAL COMMUNICATIONS, 1965, (21) :543-&

[2] STRUCTURES OF 2 NITROGEN-CONTAINING ORGANOMETALLIC COMPLEXES [J].

BAIKIE, PE ;

MILLS, OS .

CHEMICAL COMMUNICATIONS, 1966, (20) :707-&

[3] ABSORPTION IR DU GROUPE -N-N- EN COLORANTS AZOIQUES [J].

BASSIGNANA, P ;

COGROSSI, C .

TETRAHEDRON, 1964, 20 (11) :2361-&

[4]

BEADLE PJ, 1967, INORG NUCL CHEM LETT, V3, P245

[5]

BENNETT RP, 1968, 155 NAT M AM CHEM SO

[6] ELECTRONIC STRUCTURE AND SPECTRA OF CIS- AND TRANS-AZOBENZENE [J].

BEVERIDGE, DL ;

JAFFE, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (09) :1948-+

[7]

BREECH WF, 1940, J CHEM SOC, P608

[8] MOSSBAUER ELECTRONIC AND FAR INFRARED SPECTRAL STUDIES OF SOME TETRAHEDRAL IRON(2) COMPLEXES [J].

BURBRIDGE, CD ;

GOODGAME, DM .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (05) :1074-+

[9] FAR INFRA-RED SPECTRA OF 3- AND 4-ALKYLPYRIDINE COMPLEXES OF SOME TRANSITION METAL CATIONS [J].

BURGESS, J .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1968, A 24 (03) :277-&

[10] LINKAGE ISOMERISM IN METAL COMPLEXES [J].

BURMEISTER, JL .

COORDINATION CHEMISTRY REVIEWS, 1968, 3 (02) :225-+

← 1 2 3 4 5 6 7 8 →