TEMPERATURES OF TESLA DISCHARGES FROM OH A-]X INTENSITY MEASUREMENTS

被引:12
作者
HUI, AK
MCKEEVER, MR
TELLINGHUISEN, J
机构
[1] Department of Chemistry, Vanderbilt University, Nashville
关键词
D O I
10.1016/0022-4073(79)90001-3
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The OH A2Σ+ → X2Π system is used as a diagnostic tool for temperature measurements of Tesla discharges in Ar and He seeded with 0.5 torr H2O. From relative intensities of low-N′ lines in the 0-0 band we obtain temperatures which are independent of pressure for the range 100-650 torr and which are only a few degrees higher than the estimated wall temperatures. A check on the theoretical line strengths for OH A → X shows 1% agreement for main-branch transitions but only 5% agreement for satellite lines. Self-absorption problems are encountered and corrected for in the He discharge work; from the ≈10% magnitude of the correction, there are significant amounts (8 mtorr) of ground-state OH produced in the He Tesla discharge. © 1979.
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收藏
页码:387 / 396
页数:10
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