DITERPENE SYNTHESIS .1. COPPER(I)-CATALYZED 1,6-ADDITION OF A BENZYL GRIGNARD-REAGENT TO A DIENONE

被引：19

作者：

DAVIS, BR

JOHNSON, SJ

机构：

[1] Department of Chemistry, University of Auckland, Auckland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 11期

关键词：

D O I：

10.1039/p19790002840

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper(I) salts catalyse the 1,6-conjugate addition reaction of m- and p-methoxybenzylmagnesium halides to the monocyclic linear dienone (6) at the expense of 1,2- and 1,4-addition. An improved synthesis of the dienone is reported.

引用

页码：2840 / 2844

页数：5

共 15 条

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