CONTRIBUTIONS TO THE CHEMISTRY OF SILICON SULFUR-COMPOUNDS .61. THE 1ST NEUTRAL MONOMERIC COPPER(I) THIOLATE COMPLEX - CRYSTAL AND MOLECULAR-STRUCTURE OF (1,10-PHENANTHROLINE)(TRI-TERT-BUTOXYSILANETHIOLATO) COPPER(I), [CU(SSI(OC4H9-T)3)(PHEN)]

被引：23

作者：

BECKER, B

WOJNOWSKI, W

PETERS, K

PETERS, EM

VONSCHNERING, HG

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY

[2] GDANSK TECH UNIV,DEPT CHEM,PL-80952 GDANSK,POLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)83316-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [Cu{SSi(OC4H9-t)3}(phen)] (1), the first monomeric neutral copper(I) thiolate complex was obtained by reaction of 1,10-phenanthroline with [(t-BuO)3SiSCu]4 in benzene and its crystal structure determined. The copper atom is three-fold coordinated to one sulphur atom and two nitrogen atoms in a nearly trigonal planar arrangement. The relevant bond distances and angles are Cu-N 203.1(2) and 210.8(3) pm, Cu-S 214.0(1) pm, S-Si 208.6(1) pm, N-Cu-N 80.9(1)-degrees, N-Cu-S 133.5(1)-degrees and 144.6(1)-degrees, and Cu-S-Si 102.1(1)-degrees.

引用

页码：613 / 616

页数：4

共 3 条

[1] CONTRIBUTIONS TO THE CHEMISTRY OF SILICON SULFUR-COMPOUNDS .57. SYNTHESIS, MOLECULAR-STRUCTURE AND PROPERTIES OF CYCLO-TETRAKIS-[TRI-TERT-BUTOXYSILANETHIOLATOCOPPER(I)], [(T-C4H9O)3SISCU]4, THE 1ST EXAMPLE OF A SQUARE-PLANAR CU4S4 RING [J].