GOLD(I) COMPLEXES WITH THIOLATE AND TRIPHENYLPHOSPHINE LIGANDS

被引:29
作者
DELGADO, E
HERNANDEZ, E
机构
[1] Departamento de Química Inorgánica, Universidad Autónoma de Madrid
关键词
D O I
10.1016/S0277-5387(00)83654-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
There action of [AuCl(PPh3)] with Pb(SR)2(R = C2H5, C6H5, CH2C6H5, C6F5, C6H2Me3-2,4,6, Pr(i) and Bu(t)) provides a clean method to obtain complexes of the type [Au(SR)(PPh3)] in good yields. The new compounds have been characterized by IR, H-1, P-31, F-19 and 31C NMR. A study by FAB mass spectrometry indicates that an ion-molecule aggregation process takes place.
引用
收藏
页码:3135 / 3138
页数:4
相关论文
共 19 条