DILITHIUM DERIVATIVES OF BIS(TERT-BUTYLDIMETHYLSILYLAMINO)SILANES AS BUILDING UNITS FOR INORGANIC RING COMPOUNDS

被引：17

作者：

HEMME, I ^{[1
]}

TECKLENBURG, B ^{[1
]}

NOLTEMEYER, M ^{[1
]}

KLINGEBIEL, U ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1995年 / 128卷 / 04期

关键词：

BIS(SILYLAMINO)SILANES; LITHIUM COMPOUNDS;

D O I：

10.1002/cber.19951280406

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bis[(tert-butyldimethylsilyl)amino]silanes 1-3 are converted into their lithium derivatives 4-7 with BuLi. Depending on the bulkiness of the substituents, the dilithium derivatives 4 and 5 crystallize in cis or trans conformation. Monolithiated 3 (6) forms a four-membered (SiFLiN) ring system.

引用

页码：351 / 355

页数：5

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