STUDY OF THE ANODE-ELECTROLYTE INTERFACE IN A THERMAL BATTERY

被引:16
作者
NISSEN, DA
机构
[1] Sandia Laboratories, Livermore
关键词
discharge; fused salts; overvoltage;
D O I
10.1149/1.2129001
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A self-consistent anode mechanism is proposed for the Ca/LiCl-KCl/ CaCrO4 thermal battery based on the results of single cell discharges and chemical analysis of the reaction products at the electrode-electrolyte interface. The proposed mechanism involves a combination of chemical reaction between the calcium anode and the lithium chloride in the electrolyte and electrochemical oxidation of the resulting calcium-lithium alloy. © 1979, The Electrochemical Society, Inc. All rights reserved.
引用
收藏
页码:176 / 180
页数:5
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