SYNTHESIS OF CYCLOMETALLATED COMPLEXES OF PD(II) - THE X-RAY CRYSTAL-STRUCTURE OF DI-MU-BROMO-BIS[N-(3,4-DIMETHOXYBENZYLIDENE)CYCLOHEXYLAMINATO-C6,N]DIPALLADIUM(II)

被引：67

作者：

VILA, JM ^{[1
]}

GAYOSO, M ^{[1
]}

PEREIRA, MT ^{[1
]}

ROMAR, A ^{[1
]}

FERNANDEZ, JJ ^{[1
]}

THORNTONPETT, M ^{[1
]}

机构：

[1] UNIV LEEDS, SCH CHEM, LEEDS LS2 9JT, W YORKSHIRE, ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 401卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86235-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the cyclometallated bromo-bridged palladium(II) dimer complex [Pd activated {3,4-(MeO)2C6H2C(H) = NCy}(Br)]2 is described. This is the first example of a structurally characterised cyclometallated bromo-bridged dimer. Crystals were triclinic, space group P1BAR with a = 788.7(2), b = 911.0(3), c = 1480.(4) pm, alpha = 96.94(2), beta = 91.57(2), gamma = 101.85(2)-degrees, Z = 1, U = 1.0322(5) nm3, R = 0.0688, R(W) = 0.790, for 3280 independent reflections with F > 4.0-sigma(F). The structure is a centrosymmetric palladium dimer with two asymmetrically bridging bromine atoms and non-bonding Pd...Pd distance of 363.1(5) pm. The synthesis of the iodo-bridged analogue and the reactions of these two dimers and the chloro-bridged analogue with various tertiary phosphines are also described.

引用

页码：385 / 394

页数：10

共 30 条

[1]

ADAMS DM, 1966, J CHEM SOC CHEM COMM, P69

[2] REACTIONS OF CYCLOPALLADATED BENZYLIDENE-ANILINE SCHIFF-BASE COMPLEXES - SELECTIVE SYNTHESIS OF 2'-SUBSTITUTED SCHIFF-BASE DERIVATIVES AND THE X-RAY CRYSTAL-STRUCTURE OF THE DIMER [PD(MU-OAC)(5'-OCH3-C6H3CH=NC6H4-4-CH3)]2 [J].

ALBINATI, A ;

PREGOSIN, PS ;

RUEDI, R .

HELVETICA CHIMICA ACTA, 1985, 68 (07) :2046-2061

[3] CYCLOMETALATION REACTIONS [J].

BRUCE, MI .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (02) :73-86

[4] CRYSTAL AND MOLECULAR STRUCTURES OF BENZYLIDENEANILINE, BENZYLIDENEANILINE PARA CARBOXYLIC ACID AND PARA METHYLBENZYLIDENE PARA NITROANILINE [J].

BURGI, HB ;

DUNITZ, JD .

HELVETICA CHIMICA ACTA, 1970, 53 (07) :1747-&

[5] DI-MU-CHLORO-BIS[(BENZOPHENONE PHENYLHYDRAZONIDO-N,C)PALLADIUM(II)] [J].

CLARK, PW ;

DYKE, SF ;

SMITH, G ;

KENNARD, CHL ;

WHITE, AH .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 :1742-1745

[6] TRANSITION-METAL-CARBON BONDS .45. ATTEMPTS TO CYCLOPALLADATE SOME ALIPHATIC OXIMES, NN-DIMETHYLHYDRAZONES, KETAZINES, AND OXIME O-ALLYL ETHERS - CRYSTAL-STRUCTURES OF [PD2(CH2C(CH3)2C(=NOH)CH3)2CL2] AND [PD(CH2C(=NNME2)C(CH3)3)(ACAC)] [J].

CONSTABLE, AG ;

MCDONALD, WS ;

SAWKINS, LC ;

SHAW, BL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (10) :1992-2000

[7] REACTIVITY OF CYCLOPALLADATED COMPOUNDS .4. CRYSTAL AND MOLECULAR-STRUCTURES OF TETRA-NORMAL-BUTYLAMMONIUM CHLOROBROMO(N-(PHENYLAMINO)-ALPHA-METHYLBENZYLIDENIMINO-2-C,N)PALLADATE(II) AND TRANS-CHLORO(N-(PHENYLAMINO)-ALPHA-METHYLBENZYLIDENIMINO-2-C,N)BIS-(TRIETHYLPHOSPHINE)PALLADIUM(II) [J].

DEHAND, J ;

FISCHER, J ;

PFEFFER, M ;

MITSCHLER, A ;

ZINSIUS, M .

INORGANIC CHEMISTRY, 1976, 15 (11) :2675-2681

[8] GENERAL-PRINCIPLES AND CHARACTERISTICS OF CYCLOPALLADATION [J].

DUNINA, VV ;

ZALEVSKAYA, OA ;

POTAPOV, VM .

USPEKHI KHIMII, 1988, 57 (03) :434-473

[9] CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-MU-DICHLORO-BIS(PHENYLAZOPHENYL-2C,N')DIPLATINUM(II) [J].

ELDER, RC ;

CRUEA, RDP ;

MORRISON, RF .

INORGANIC CHEMISTRY, 1976, 15 (07) :1623-1626

[10] DYNAMIC BEHAVIOR OF CARBON-METALLATED PALLADIUM HYDRAZONE COMPLEXES - CRYSTAL-STRUCTURES OF [(PD[CH2CME2C(=N-NMEPH)ME]CL)2] AND [(PD[CH2C(=N-NMEPH)BUT]CL)2] [J].

GALLI, B ;

GASPARRINI, F ;

MANN, BE ;

MARESCA, L ;

NATILE, G ;

MANOTTILANFREDI, AM ;

TIRIPICCHIO, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06) :1155-1161

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