COORDINATION-SPHERE DYNAMICS OF BISPHOSPHINE ORTHO-SEMIQUINONE COMPLEXES OF COPPER(I)

被引：10

作者：

ABAKUMOV, GA

CHERKASOV, VK

NEVODCHIKOV, VI

GARNOV, VA

机构：

[1] Institute of Organometallic Chemistry, Academy of Sciences of the USSR, Gor'kii

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 09期

关键词：

D O I：

10.1007/BF00960398

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Depending on steric effects of phosphine and o-semiquinone (SQ) ligands bonded to the copper atom, (R3P)2CuSQ complexes have either pseudotetrahedral geometry with equivalent phosphine ligands or trigonal-pyramidal with one equatorial and one axial phosphine ligand. In an ESR study of the exchange dynamics of the phosphine ligands in trigonal-pyramidal complexes, the kinetic parameters of the exchange were determined. A model was proposed which explains distortions in the geometry of the complexes by nonvalence interatomic interactions on the "periphery" of the phosphine and SQ ligands.

引用

页码：1754 / 1759

页数：6

共 7 条

[1]

ABAKUMOV GA, 1980, DOKL AKAD NAUK SSSR+, V251, P103

[2]

CHERKASOV VK, 1985, 6TH EUR C ORG CHEM R, P108

[3] ACETATOBIS(TRIPHENYLPHOSPHINE)COPPER(I) [J].