SYNTHESIS AND CRYSTAL-STRUCTURE OF CABIVO5

被引：28

作者：

BOJE, J ^{[1
]}

MULLERBUSCHBAUM, H ^{[1
]}

机构：

[1] UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,W-2300 KIEL 1,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 03期

关键词：

CALCIUM; BISMUTH; VANADIUM; OXIDE; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19936190315

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of the hitherto unknown compound CaBiVO5 were prepared and investigated by X-ray work. It crystallizes with orthorhombic symmetry, space group D2h15-Pbca, a = 11.2022, b = 5.4283, c = 15.5605 angstrom, Z = 8. The crystal structure is characterized by layers of the edge-linked CaO7 polyhedra, isolated VO4 tetrahedra and an asymmetric surrounding of Bi3+ by oxygen.

引用

页码：521 / 524

页数：4

共 8 条

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[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (03): : 525 - 528
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