X-RAY-DIFFRACTION AND SPECTROSCOPIC INVESTIGATIONS OF PHASE-TRANSITIONS IN LINEAR-CHAIN COMPOUNDS M2[PT(CN)4]3.21H2O, WITH M=DY, ER, TB, Y

被引：29

作者：

DANIELS, W

YERSIN, H

PHILIPSBORN, HV

GLIEMANN, G

机构：

[1] Institut für Chemie, Universität Regensburg

来源：

SOLID STATE COMMUNICATIONS | 1979年 / 30卷 / 06期

关键词：

D O I：

10.1016/0038-1098(79)90650-1

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Phase transitions of single-crystal M2 [Pt(CN)4]3 · 21H2O are investigated under temperature variation using X-ray diffraction, polarized emission and DSC-measurements. At a temperature Ttrans a jump was observed in lattice parameters and in optical transition energies. The transition is connected with an occurence of a latent transition enthalpy. This indicates a displacive phase transition of first order. Optical and X-ray data can be correlated. © 1979.

引用

页码：353 / 355

页数：3

共 7 条

[1] DANIELS W, 1977, THESIS REGENSBURG
[2] POLARIZED EMISSION STUDIES AND CRYSTAL DATA OF KLI[PT(CN)4] . 2H2O
HOLZAPFEL, W
YERSIN, H
GLIEMANN, G
OTTO, HH
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1978, 82 (02): : 207 - 212
[3] RASSENFOSSE AD, 1935, B SOC SCI LIEGE, V4, P277
[4] TOLSTOI NA, 1956, B ACAD SCI USSR PHYS, V20, P529
[5] PHASE-TRANSFORMATION IN Y2[PT(CN)4]3 H2O-H-21
YERSIN, H
GLIEMANN, G
RADE, HS
[J]. CHEMICAL PHYSICS LETTERS, 1978, 54 (01) : 111 - 116
[6] YERSIN H, 1972, MESSTECHNIK, V80, P99
[7] YERSIN H, 1978, SYNTHESIS PROPERTIES, V313, P539

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