PEROXIDES OF ELEMENTS OTHER THAN CARBON .15. AUTOXIDATION OF EPIMERIC TRINORBORNYLBORANES

被引：65

作者：

DAVIES, AG

ROBERTS, BP

机构：

[1] William Ramsay and Ralph Forster Laboratories, University College

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 03期

关键词：

D O I：

10.1039/j29690000311

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three epimeric mixtures of trinorbornylboranes have been prepared, in which the percentages of exo- and endonorbornyl groups are 99.2 and 0.8%, 66 and 34%, and 14 and 86%, respectively. All three react with oxygen to give norbornylbis(norbornylperoxy)borane containing about 76% exo- and 24% endo-norbornyl-oxygen links, and the reactions are inhibited by galvinoxyl, copper NN-dibutyldithiocarbamate, and phenothiazine. It is proposed that the autoxidations follow a homolytic chain mechanism involving a common norbornyl radical.

引用

页码：311 / &

共 17 条

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