TOUGHENING MECHANISMS IN CORE SHELL RUBBER MODIFIED POLYCARBONATE

被引:199
作者
PARKER, DS [1 ]
SUE, HJ [1 ]
HUANG, J [1 ]
YEE, AF [1 ]
机构
[1] UNIV MICHIGAN,DEPT MAT SCI & ENGN,ANN ARBOR,MI 48109
关键词
core-shell rubber; fracture toughness; polycarbonate; rubber modification; toughening;
D O I
10.1016/0032-3861(90)90312-M
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We have conducted a study of toughening mechanisms in rubber modified polycarbonate systems in order to evaluate the sequence of deformation events which improve fracture toughness. We conclude that cavitation of the rubber particles occurs first, followed by massive shear yielding of the matrix material. The size and shape of the deformation zone created in front of the crack is governed by the mechanical properties of the rubber particles and the stress state at the crack tip. The importance of using a variety of analytical techniques to characterize deformation mechanism is also illustrated. © 1990.
引用
收藏
页码:2267 / 2277
页数:11
相关论文
共 31 条
[1]  
ARGON AS, 1983, ADV POLYM SCI, V52-3, P275
[2]  
ARGON AS, 1989, ADV FRACTURE RES, V4, P2661
[3]  
BASCOM WD, 1981, J MATER SCI, V16, P2657, DOI 10.1007/BF02402827
[4]  
BORGGREVE RJM, 1985, POLYMER, V30, P78
[5]  
BREUER H, 1977, J MACROMOL SCI PHYS, VB14, P387, DOI 10.1080/00222347708212908
[6]  
Bucknall C. B., 1977, TOUGHENED PLASTICS, DOI DOI 10.1007/978-94-017-5349-4
[7]   TOUGHENED BLENDS OF POLY(BUTYLENE TEREPHTHALATE) AND BPA POLYCARBONATE .2. TOUGHENING MECHANISMS [J].
DEKKERS, MEJ ;
HOBBS, SY ;
WATKINS, VH .
JOURNAL OF MATERIALS SCIENCE, 1988, 23 (04) :1225-1230
[8]   MECHANISMS OF TOUGHENING IN RUBBER TOUGHENED POLYMERS [J].
EVANS, AG ;
AHMAD, ZB ;
GILBERT, DG ;
BEAUMONT, PWR .
ACTA METALLURGICA, 1986, 34 (01) :79-87
[9]  
HOLIK AS, 1979, 11TH P ANN TECHN M I, P357
[10]   INTERPRETATION OF FRACTURE SURFACE FEATURES IN POLYCARBONATE [J].
HULL, D ;
OWEN, TW .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1973, 11 (10) :2039-2055