UNUSUAL EPSILON/GAMMA-REGIOSPECIFICITY OF (E/Z)-PENTADIENYLTIN IN THE LEWIS ACID-PROMOTED REACTION WITH AN ALDEHYDE

被引：12

作者：

NISHIGAICHI, Y

FUJIMOTO, M

TAKUWA, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 20期

关键词：

D O I：

10.1039/p19920002581

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the Lewis acid-promoted reaction between pentadienyltin (PDT) and an aldehyde, (E)- and (Z)-PDTs exhibit opposite regioreactivities: (E)-PDT reacts at the terminal epsilon-position and (Z)-PDT at the internal gamma-position.

引用

页码：2581 / 2582

页数：2

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