TOUGHENING OF HIGHLY CROSS-LINKED POLYCYANURATES WITH EPOXY-TERMINATED AND PHENOL-TERMINATED BUTADIENE-ACRYLO-NITRILE RUBBERS

被引:19
作者
UHLIG, C
BAUER, J
BAUER, M
机构
[1] Fraunhofer Institute of Applied Materials Research, Teltow, 14513
关键词
D O I
10.1002/masy.19950930111
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polycyanurate from dicyanate of bisphenol A was modified with epoxy- and phenol-terminated butadiene-acrylonitrile rubbers. Rubber-resin-copolymerisation was followed by multiple-detection gel-permeation chromatography (GPC). It was found that both the epoxy-terminated and phenol-terminated rubbers react with the cyanate and thus are covalently bound with the polycyanurate network. The influence of rubber content, acrylonitrile content and type of end group on phase structure was investigated using dynamic mechanical analysis. Fracture toughness was measured for these modifications.
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页码:69 / 79
页数:11
相关论文
共 19 条
[1]  
ALLA C, 1992, THESIS U P M CURIE P
[2]  
BARTLET P, 1989, J APPL POLYM SCI, V30, P2955
[3]   KINETIC STRUCTURAL MODEL FOR THE NETWORK BUILDUP DURING THE REACTION OF CYANIC ACID-ESTERS WITH GLYCIDYL ETHERS [J].
BAUER, J ;
BAUER, M .
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1990, A27 (01) :97-116
[4]   KINETIC STRUCTURAL MODEL FOR THE NETWORK BUILDUP DURING THE REACTION OF CYANIC ACID-ESTERS WITH GLYCIDYL ETHERS .2. APPLICATION TO DCBA/DGEBA-SYSTEMS [J].
BAUER, J ;
BAUER, M .
ACTA POLYMERICA, 1990, 41 (10) :535-538
[5]  
Bauer J. H., UNPUB
[6]   REACTIONS OF POLYFUNCTIONAL ESTERS OF CYANIC ACID WITH POLYFUNCTIONAL GLYCIDYLETHERS .2. REACTION MODEL [J].
BAUER, M ;
BAUER, J ;
RUHMANN, R ;
KUHN, G .
ACTA POLYMERICA, 1989, 40 (06) :397-401
[7]   NETWORKS FROM DICYANATE OF BISPHENOL-A AND DIPHENOLS [J].
BAUER, M ;
BAUER, J ;
JAHRIG, S .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1991, 45 :97-103
[8]   NETWORKS FROM CYANIC ACID-ESTERS AND GLYCIDYL ETHERS [J].
BAUER, M ;
BAUER, J .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1989, 30 :1-11
[9]  
Bauer M., 1994, CHEM TECHNOLOGY CYAN, P58, DOI [10.1007/978-94-011-1326-7_3, DOI 10.1007/978-94-011-1326-7_3]
[10]   TOUGHENING OF POLYESTER RESINS BY RUBBER MODIFICATION .1. MECHANICAL-PROPERTIES [J].
CROSBIE, GA ;
PHILLIPS, MG .
JOURNAL OF MATERIALS SCIENCE, 1985, 20 (01) :182-192