NEW BRIDGING MODE OF CARBON-DISULFIDE IN A DINUCLEAR COBALT(1) COMPLEX

被引：14

作者：

BIANCHINI, C ^{[1
]}

MEALLI, C ^{[1
]}

MELI, A ^{[1
]}

ORLANDINI, A ^{[1
]}

SACCONI, L ^{[1
]}

机构：

[1] UNIV FLORENCE,IST CHIM GEN & INORGAN,CNR,I-50132 FLORENCE,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 09期

关键词：

D O I：

10.1002/anie.197906731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unsymmetrical CS2 bridge between two Co atoms is found in the dication [(triphos)Co1(CS2)Co1(triphos)]2+. According to X‐ray structure alalysis, one Co atome is π‐bonded to a CS group while the other one forms two σ‐bonds to the two S atoms. Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：673 / 674

页数：2

共 10 条

[1] BIANCHINI C, UNPUBLISHED
[2] CHEMISTRY OF METAL-CARBONYL ANIONS .6. PREPARATION AND PROPERTIES OF METALLODITHIOCARBOXYLATE ANIONS
ELLIS, JE
FENNELL, RW
FLOM, EA
[J]. INORGANIC CHEMISTRY, 1976, 15 (09) : 2031 - 2036
[3] FEHLHAMMER WP, 1979, ANGEW CHEM INT EDIT, V18, P626, DOI 10.1002/anie.197906261
[4] FEHLHAMMER WP, 1979, ANGEW CHEM, V91, P661
[5] INTRAMOLECULAR MOBILITY IN CS2 COMPLEXES OF MANGANESE
HERBERHOLD, M
SUSSFINK, M
KREITER, CG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (03): : 193 - 194
[6] HERBERHOLD M, 1977, ANGEW CHEM, V89, P191
[7] PLATINUM(II) COMPLEX CONTAINING A METALLODITHIOCARBOXYLATE LIGAND
LISY, JM
DOBRZYNSKI, ED
ANGELICI, RJ
CLARDY, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (03) : 656 - 657
[8] HETERODINUCLEAR COMPOUNDS WITH CARBON-DISULFIDE BRIDGES FECS2MN AND FECS2MO - USE OF ETA2-CS2-IRON COMPLEXES AS LIGANDS
OEHMICHEN, U
SOUTHERN, TG
LEBOZEC, H
DIXNEUF, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 156 (02) : C29 - C32
[9] BASE METALS .9. SYNTHESIS AND CRYSTAL-STRUCTURE OF C5H5CO(PME3)CS2 - REACTIONS TO BINUCLEAR COMPLEXES WITH CO(SCS)CR AND CO(SCS)MN BRIDGE BONDS
WERNER, H
LEONHARD, K
BURSCHKA, C
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (01) : 291 - 298
[10] THIOCARBONYL AND RELATED COMPLEXES OF TRANSITION-METALS
YANEFF, PV
[J]. COORDINATION CHEMISTRY REVIEWS, 1977, 23 (02) : 183 - 220

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