CATALYTIC ASYMMETRIC OXIDATION OF SULFIDES USING (SALEN)MANGANESE(III) COMPLEX AS A CATALYST

被引：108

作者：

NODA, K ^{[1
]}

HOSOYA, N ^{[1
]}

IRIE, R ^{[1
]}

YAMASHITA, Y ^{[1
]}

KATSUKI, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON | 1994年 / 50卷 / 32期

关键词：

D O I：

10.1016/S0040-4020(01)85529-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric oxidation of sulfides was examined by using (salen)manganese(III) complexes as catalysts and (8S,8'S, 1''S,2''S)-complex (2b) was found to show high asymmetric induction up to 90% ee. Its diastereomeric (8R,8'R,1''S,2''S)-complex (la) that showed excellent asymmetric induction in the epoxidation of simple olefins, however, was a poor catalyst for the oxidation of sulfides. Kinetic resolution of racemic methyl phenyl sulfoxide with 2b was not effective.

引用

页码：9609 / 9618

页数：10

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