STUDIES ON SOME NEW NEUTRAL TRIS-COMPLEXES OF TRIVALENT RHODIUM AND CHROMIUM

被引：16

作者：

BEHERA, B

CHAKRAVO.A

机构：

[1] Department of Chemistry, Indian Institute of Technology, Kanpur

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 06期

关键词：

D O I：

10.1016/0022-1902(69)80397-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of tris-chelates of Rh(III) and Cr(III) derived from several triazene-1-oxides is described. The electronic spectra of the complexes are discussed. A typical Cr(III)-complex is characterised by the crystal field parameters: Dq = 1740 cm-1 and B = 508 cm-1. Proton resonance data unequivocally established the trans stereochemistry for the Rh(III) complexes. The sterically unfavorable cis form could not be synthesised. © 1969.

引用

页码：1791 / &

共 27 条

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[2]

BEHERA B, UNPUBLISHED INVESTIG

[3]

BEHERA B, 1968, J AM CHEM SOC, V90, P7363

[4] COMPLEXES BETWEEN PYRIDINE-2-ALDEHYDE-2]-PYRIDYLHYDRAZAZONE AND PLATINUM METALS .I. RHODIUM [J].