VANADIUM(III) OXYCHLORIDE - MAGNETIC, OPTICAL AND ELECTRICAL-PROPERTIES - LITHIUM AND MOLECULAR INTERCALATIONS

被引：20

作者：

VENIEN, JP

PALVADEAU, P

SCHLEICH, D

ROUXEL, J

机构：

[1] (Laboratoire de Chimie des Solides, associé au CNRS (L.A. 279) Faculté des Sciences, F. 44072 Nantes Cédex

来源：

MATERIALS RESEARCH BULLETIN | 1979年 / 14卷 / 07期

关键词：

D O I：

10.1016/0025-5408(79)90154-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Single crystals of vanadium oxychloride have been prepared by reaction between VCl3 and V2O3. An antiferromagnetic behaviour is observed (TN = 150 ± 5 K). Optical and electrical measurements have shown VOCl to be a semi-conductor (∼ 2 eV). The resistivity at room temperature is 5.107Ωcm. Lithium can be intercalated electrochemically or through the butyllithium technique. A definite compound Li0.80VOCl was characterized. Pyridine leads to similar intercalates as in FeOCl. © 1979.

引用

页码：891 / 897

页数：7

共 22 条

[1] M-O-X TRANSITION-METAL OXYHALIDES - NEW CLASS OF LAMELLAR CATHODE MATERIAL [J].