FTIR CHARACTERIZATION OF CHEMICALLY-MODIFIED FIBERBOARD

被引:8
作者
ROZMAN, HD [1 ]
BANKS, WB [1 ]
LAWTHER, MI [1 ]
机构
[1] UNIV WALES,SCH AGR & FOREST SCI,BANGOR,GWYNEDD,WALES
关键词
MDF FIBER; CHEMICAL MODIFICATION; GLYCIDYL METHACRYLATE; POLYMERIZATION; INFRARED SPECTROSCOPY;
D O I
10.1080/00914039408029346
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
High temperature refined thermo-mechanical pulp (MDF fiber) was dried, extracted with neutral organic solvent and reacted with an electrophilic reagent, i.e. glycidyl methacrylate (GMA). The adducts formed were characterized by infra-red spectroscopy and further reacted in a hot press with a series of vinyl monomers in the presence of a free radical initiator (benzoyl peroxide). Well conformed boards were produced by the process. Samples of these boards were ground to a fine flour, extracted with acetone/ toluene to remove the polymers and again characterized by infra-red spectroscopy. The spectral evidence suggests that some copolymerization occurs between GMA-modified fiber and the polymer.
引用
收藏
页码:19 / 24
页数:6
相关论文
共 7 条
[1]  
BANKS WB, 1990, CELLULOSE SOURCES EX
[2]  
MATSUDA H, 1987, WOOD SCI TECHNOL, V21, P75
[3]   PREPARATION AND CROSSLINKING OF OLIGOESTERIFIED WOODS BASED ON PHTHALIC-ANHYDRIDE AND GLYCIDYL METHACRYLATE [J].
MATSUDA, H ;
UEDA, M ;
MORI, H .
WOOD SCIENCE AND TECHNOLOGY, 1988, 22 (04) :335-344
[4]   PREPARATION AND CROSSLINKING OF OLIGOESTERIFIED WOODS BASED ON MALEIC-ANHYDRIDE AND ALLYL GLYCIDYL ETHER [J].
MATSUDA, H ;
UEDA, M ;
MORI, H .
WOOD SCIENCE AND TECHNOLOGY, 1988, 22 (01) :21-32
[5]  
NAKAGAMI T, 1981, MOKUZAI GAKKAISHI, V27, P87
[6]  
Rowell R. M., 1983, Forest Products Abstracts, V6, P363
[7]  
ROWELL RM, 1980, WOOD SCI, V13, P102