Novel radical-chain deoxygenations of primary alcohols are described. The alcohols are acylated with the reagents pentafluorophenyl chlorothionoformate, 2,4,6-trichlorophenyl chlorothionoformate and 4-fluorophenyl chlorothionoformate and the intermediate thionocarbonates are deoxygenated with tributyltin hydride, triphenylsilane, diphenylsilane or phenylsilane in high-yielding reactions.
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UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLANDUNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND
ALLEN, RP
ROBERTS, BP
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UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLANDUNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND
ROBERTS, BP
WILLIS, CR
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UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLANDUNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND
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UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLANDUNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND
ALLEN, RP
ROBERTS, BP
论文数: 0引用数: 0
h-index: 0
机构:
UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLANDUNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND
ROBERTS, BP
WILLIS, CR
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h-index: 0
机构:
UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLANDUNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND